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New York City - “Gossip Girl” stars started work earlier today, August 3, 2009 in New York City, New York and had a surprise new addition to the season, Hilary Duff. She wears a nice College get up, of course there's a bag and a nice fedora hat.

Hilary will be playing Olivia Burke and ironically she is a movie star who enrolls at NYU in hopes for a normal college life experience. Olivia is rumored to become Dan’s (Penn Badgley) new lover on the show. How will Ms. Lively feel about that one?

Hilary Duff Gossip GirlPhoto Credit: FPZ/Fame Pictures